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Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a ...
After the ions have been removed from the conditioning of the circulating water (e.g. ammonium NH 4 +) in the cation exchanger, ions resulting from gaseous components must be removed in order to determine degas conductivity. These are typically gases from the atmosphere which have penetrated into the system through leaks in the water-steam circuit.
Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher the resistivity). Conductivity measurements in water are often reported as specific conductance, relative to the conductivity of pure water at 25 °C.
De-gassed cation conductivity. There is a difference between these three types of measurements. Specific conductivity gives overall conductivity value of the sample and is the most generic measurement; Cation conductivity is conductivity measurement after the Cation Column. At the Cation Column, the H+ resins replace the positive ions of all ...
κ is the measured conductivity (formerly known as specific conductance), [3] c is the molar concentration of the electrolyte. The SI unit of molar conductivity is siemens metres squared per mole (S m 2 mol −1). [2] However, values are often quoted in S cm 2 mol −1. [4]
where is the length of the conductor, measured in metres (m), A is the cross-sectional area of the conductor measured in square metres (m 2), σ is the electrical conductivity measured in siemens per meter (S·m −1), and ρ is the electrical resistivity (also called specific electrical resistance) of the material, measured in ohm-metres (Ω ...
In practice the molar ionic conductivities are calculated from the measured ion transport numbers and the total molar conductivity. For the cation + = + +, and similarly for the anion. In solutions, where ionic complexation or associaltion are important, two different transport/transference numbers can be defined.
For reaction between a weak acid and a weak base in the beginning conductivity decreases a bit as the few available H + ions are used up. Then conductivity increases slightly up to the equivalence point volume, due to contribution of the salt cation and anion of the weak acid as it is formed from and the neutral acid (This changing contribution ...