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Properties of isolated, closed, and open systems in exchanging energy and matter. In thermodynamics, a closed system can exchange energy (as heat or work) but not matter, with its surroundings. An isolated system cannot exchange any heat, work, or matter with the surroundings, while an open system can exchange energy and matter.
A closed system may exchange heat, experience forces, and exert forces, but does not exchange matter. An open system can interact with its surroundings by exchanging both matter and energy. The physical condition of a thermodynamic system at a given time is described by its state , which can be specified by the values of a set of thermodynamic ...
In 1907, George H. Bryan wrote about systems between which there is no transfer of matter (closed systems): "Definition. When energy flows from one system or part of a system to another otherwise than by the performance of mechanical work, the energy so transferred is called heat."
In a closed system (i.e. there is no transfer of matter into or out of the system), the first law states that the change in internal energy of the system (ΔU system) is equal to the difference between the heat supplied to the system (Q) and the work (W) done by the system on its surroundings.
The law of conservation of energy states that the total energy of an isolated system remains constant; it is said to be conserved over time. [1] In the case of a closed system, the principle says that the total amount of energy within the system can only be changed through energy entering or leaving the system.
One such potential is the Helmholtz free energy (A), for a closed system at constant volume and temperature (controlled by a heat bath): = Another potential, the Gibbs free energy (G), is minimized at thermodynamic equilibrium in a closed system at constant temperature and pressure, both controlled by the surroundings:
An isolated system has a fixed total energy and mass. A closed system, on the other hand, is a system which is connected to another, and cannot exchange matter (i.e. particles), but can transfer other forms of energy (e.g. heat), to or from the other system.
In thermodynamics, a closed system is one that cannot take in or give out ponderable matter, but may be able to take in or give out radiation and heat and work or any form of energy. In thermodynamics, a closed system can be further restricted, by being 'isolated': an isolated system cannot take in nor give out either ponderable matter or any ...