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An example of a dative covalent bond is provided by the interaction between a molecule of ammonia, a Lewis base with a lone pair of electrons on the nitrogen atom, and boron trifluoride, a Lewis acid by virtue of the boron atom having an incomplete octet of electrons. In forming the adduct, the boron atom attains an octet configuration.
[5] [page needed] The bonds formed between these ligands and the metal are dative covalent bonds, which are also known as coordinate bonds. Examples of this type of ligand include CO, PR 3, NH 3, H 2 O, carbenes (=CRR'), and alkenes. Z-type ligands are those that accept two electrons from the metal center, as opposed to the donation occurring ...
In organic chemistry, covalent bonding is much more common than ionic bonding. Covalent bonding also includes many kinds of interactions, including σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds, three-center two-electron bonds and three-center four-electron bonds. [2] [3] The term covalent bond dates from 1939 ...
Although there have been attempts to use computational and experimental energetic criteria to distinguish dative bonding from non-dative covalent bonds, [4] for the most part, the distinction merely makes note of the source of the electron pair, and dative bonds, once formed, behave simply as other covalent bonds do, though they typically have ...
Owing to the vacant orbital present in Z-ligands, many have incomplete octets which allow them to readily accept a pair of electrons from other atoms. [1] A Z‑function ligand interacts with a metal center via a dative covalent bond, differing from the L‑function in that both electrons are donated by the metal rather than the ligand. [5]
The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond with it. Typical examples are listed in the following table. Typical examples are listed in the following table.
The bond between a water molecule and the metal ion is a dative covalent bond, with the oxygen atom donating both electrons to the bond. Each coordinated water molecule may be attached by hydrogen bonds to other water molecules. The latter are said to reside in the second coordination sphere.
Intermediate organization of covalent bonds: Regarding the organization of covalent bonds, recall that classic molecular solids, as stated above, consist of small, non-polar covalent molecules. The example given, paraffin wax, is a member of a family of hydrocarbon molecules of differing chain lengths, with high-density polyethylene at the long ...