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Francium-223 also has a shorter half-life than the longest-lived isotope of each synthetic element up to and including element 105, dubnium. [8] Francium is an alkali metal whose chemical properties mostly resemble those of caesium. [8] A heavy element with a single valence electron, [9] it has the highest equivalent weight of any element. [8]
The CsFr molecule is predicted to have francium at the negative end of the dipole, unlike all known heterodiatomic alkali metal molecules. Francium superoxide (FrO 2) is expected to have a more covalent character than its lighter congeners; this is attributed to the 6p electrons in francium being more involved in the francium–oxygen bonding. [4]
What little is known about francium shows that it is very close in behaviour to caesium, as expected. The physical properties of francium are even sketchier because the bulk element has never been observed; hence any data that may be found in the literature are certainly speculative extrapolations. [64]
{{Infobox element}}; labels & notes: (Image) GENERAL PROPERTIES Name Symbol Pronunciation (data central) Alternative name(s) Allotropes Appearance <element> IN THE PERIODIC TABLE Periodic table Atomic number Standard atomic weight (data central) Element category (also header bg color) (sets header bg color, over 'series='-color) Group Period ...
However, it would appear that francium perchlorate has been formed, as it coprecipitates with caesium perchlorate, and several other insoluble francium salts are similarly known (Hyde, E.K., Radiochemical Methods for the Isolation of Element 87 (Francium), J. Am. Chem. Soc., 1952, 74, 4181) The article also quotes a value for the Pauling ...
Francium (87 Fr) has no stable isotopes, thus a standard atomic weight cannot be given. Its most stable isotope is 223 Fr with a half-life of 22 minutes, occurring in trace quantities in nature as an intermediate decay product of 235 U. Of elements whose most stable isotopes have been identified with certainty, francium is the most unstable.
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Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.