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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
This page provides supplementary chemical data on boric acid. Thermodynamic properties. Phase behavior Triple point? K (? °C), ? Pa Critical point? K (? °C), ?
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise. The substances are listed in alphabetical order.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In aqueous solution, boric acid B(OH) 3 can act as a weak Brønsted acid, that is, a proton donor, with pK a ~ 9. However, it more often acts as a Lewis acid , accepting an electron pair from a hydroxide ion produced by the water autoprotolysis : [ 11 ]
Commonly used mineral acids are sulfuric acid (H 2 SO 4), hydrochloric acid (HCl) and nitric acid (HNO 3); these are also known as bench acids. [1] Mineral acids range from superacids (such as perchloric acid) to very weak ones (such as boric acid). Mineral acids tend to be very soluble in water and insoluble in organic solvents.
A dehydrating agent, such as concentrated sulfuric acid is typically added. [1] Borate esters are volatile and can be purified by distillation. This procedure is used for analysis of trace amounts of borate and for analysis of boron in steel. [2] Like all boron compounds, alkyl borates burn with a characteristic green flame.
The simplest way to prepare a BBS solution is to use BBS tablets. They are formulated to give a ready to use borate buffered saline solution upon dissolution in 500 ml of deionized water. Concentration of borate and NaCl as well as the pH can vary, and the resulting solution would still be referred to as "borate buffered saline".