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Thermoplastic vulcanizates were first reported in 1962 by A.M. Gessler and W.H. Haslett. [4] In 1973, W.K. Fisher reported the dynamic vulcanization process through his prior work on polypropylene and EPDM rubber-based TPVs with peroxides as a cross-linking agent.
Kraton polymers are styrenic block copolymer (SBC) consisting of polystyrene blocks and rubber blocks. The rubber blocks consist of polybutadiene, polyisoprene, or their hydrogenated equivalents. The tri-block with polystyrene blocks at both extremities linked together by a rubber block is the most important polymer structure observed in SBC.
Worker placing a tire in a mold before vulcanization. Vulcanization (British English: vulcanisation) is a range of processes for hardening rubbers. [1] The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to include the hardening of other (synthetic ...
RTV silicone (room-temperature-vulcanizing silicone) is a type of silicone rubber that cures at room temperature. It is available as a one-component product, or mixed from two components (a base and curative).
EPDM rubber (ethylene propylene diene monomer rubber) [1] [2] [3] is a type of synthetic rubber that is used in many applications. EPDM is an M-Class rubber under ASTM standard D-1418; the M class comprises elastomers with a saturated polyethylene chain (the M deriving from the more correct term polymethylene).
Ebonite is a brand name for a material generically known as hard rubber or vulcanite, obtained via vulcanizing natural rubber for prolonged periods. Ebonite may contain from 25% to 80% sulfur and linseed oil. [1] [2] Its name comes from its intended use as an artificial substitute for ebony wood.
The strand concentration, v, is the number of strands over the volume which does not depend on the overall size and shape of the elastomer. [4] Beta relates the end-to-end distance of polymer strands across crosslinks over polymers that obey random walk statistics.
Sulfur vulcanization is a chemical process for converting natural rubber or related polymers into materials of varying hardness, elasticity, and mechanical durability by heating them with sulfur [citation needed] or sulfur-containing compounds. [1]