Search results
Results From The WOW.Com Content Network
Phosphides arise by reaction of metals with red phosphorus. The alkali metals (group 1) and alkaline earth metals can form ionic compounds containing the phosphide ion, P 3−. These compounds react with water to form phosphine. Other phosphides, for example Na 3 P 7, are known for these reactive metals.
In aqueous solutions (solutions of water), water gradually (over the course of hours) hydrolyzes polyphosphates into smaller phosphates and finally into ortho-phosphate, given enough water. Higher temperature or acidic conditions can speed up the hydrolysis reactions considerably.
White phosphorus, yellow phosphorus, or simply tetraphosphorus (P 4) is an allotrope of phosphorus. It is a translucent waxy solid that quickly yellows in light (due to its photochemical conversion into red phosphorus ), [ 2 ] and impure white phosphorus is for this reason called yellow phosphorus.
Phosphorus trichloride is commonly used to convert primary and secondary alcohols to the corresponding chlorides. [14] As discussed above, the reaction of alcohols with phosphorus trichloride is sensitive to conditions. The mechanism for the ROH →RCl conversion involves the reaction of HCl with phosphite esters: P(OR) 3 + HCl ⇌ HP(OR) + 3 ...
White phosphorus, yellow phosphorus or simply tetraphosphorus (P 4) exists as molecules of four phosphorus atoms in a tetrahedral structure, joined by six phosphorus—phosphorus single bonds. [1] The free P 4 molecule in the gas phase has a P-P bond length of r g = 2.1994(3) Å as was determined by gas electron diffraction . [ 2 ]
Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula P O Cl 3. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride. It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide. [4] It is mainly used to make ...
The Michaelis–Arbuzov reaction is initiated with the S N 2 attack of the nucleophilic phosphorus species (1 - A phosphite) with the electrophilic alkyl halide (2) to give a phosphonium salt as an intermediate (3). These intermediates are occasionally stable enough to be isolated, such as for triaryl phosphites which do not react to form the ...
This reaction is used for laboratory-scale preparations of PH 3. Phosphorous acid slowly oxidizes in air to phosphoric acid. [5] Both phosphorous acid and its deprotonated forms are good reducing agents, although not necessarily quick to react. They are oxidized to phosphoric acid or its salts. It reduces solutions of noble metal cations to the ...