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In chemistry, a chemical oscillator is a complex mixture of reacting chemical compounds in which the concentration of one or more components exhibits periodic changes. They are a class of reactions that serve as an example of non-equilibrium thermodynamics with far-from-equilibrium behavior.
A stirred BZ reaction mixture showing changes in color over time. The discovery of the phenomenon is credited to Boris Belousov.In 1951, while trying to find the non-organic analog to the Krebs cycle, he noted that in a mix of potassium bromate, cerium(IV) sulfate, malonic acid, and citric acid in dilute sulfuric acid, the ratio of concentration of the cerium(IV) and cerium(III) ions ...
Oscillation is the repetitive or periodic variation, typically in time, of some measure about a central value (often a point of equilibrium) or between two or more different states. Familiar examples of oscillation include a swinging pendulum and alternating current. Oscillations can be used in physics to approximate complex interactions, such ...
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
The frequency of oscillation at x is proportional to the momentum p(x) of a classical particle of energy E n and position x. Furthermore, the square of the amplitude (determining the probability density) is inversely proportional to p ( x ) , reflecting the length of time the classical particle spends near x .
The waves in quantum systems are oscillations in probability amplitude rather than material displacement. The frequency of oscillation, f, relates to the mode energy by E = hf where h is the Planck constant. Thus a system like an atom consists of a linear combination of modes of definite energy. These energies are characteristic of the ...
A simple harmonic oscillator is an oscillator that is neither driven nor damped.It consists of a mass m, which experiences a single force F, which pulls the mass in the direction of the point x = 0 and depends only on the position x of the mass and a constant k.
If the power is modulated in phase with the oscillator's velocity, a negative damping is established and the oscillation grows until limited by nonlinearities. Self-oscillation is the generation and maintenance of a periodic motion by a source of power that lacks any corresponding periodicity. The oscillator itself controls the phase with which ...