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Gold(III) chloride was first prepared in 1666 by Robert Boyle by the reaction of metallic gold and chlorine gas at 180 °C: [1] [6] [7] 2 Au + 3 Cl 2 → Au 2 Cl 6. This method is the most common method of preparing gold(III) chloride. It can also be prepared by reacting gold powder with iodine monochloride: [5] 2 Au + 6 ICl → 2 AuCl 3 + 3 I 2
Gold(I,III) chloride (gold dichloride, tetragold octachloride), Au 4 Cl 8 Gold(III) chloride (gold trichloride, digold hexachloride), Au 2 Cl 6 Chloroauric acid , HAuCl 4 (brown gold chloride); or its sodium salt, sodium tetrachloroaurate , NaAuCl 4 (gold chloride, sodium gold chloride, yellow gold chloride), used as a histological stain
The gold atom centers in Au(III) complexes, like other d 8 compounds, are typically square planar, with chemical bonds that have both covalent and ionic character. Gold(I,III) chloride is also known, an example of a mixed-valence complex. Gold does not react with oxygen at any temperature [4] and, up to 100 °C, is resistant to attack from ...
It is used as an alternative to chlorine and sodium hypochlorite for disinfection of drinking water and swimming pools. Chloramine-T, or tosylchloramide sodium salt, [(H 3 C)(C 6 H 4)(SO 2)(NHCl)] − Na +. This solid compound is available in tablet or powder form, and used in medical establishments to disinfect surfaces, equipment, and ...
Single crystals of gold(I,III) chloride are triclinic with a P 1 space group and consist of discrete Au 4 Cl 8 molecules with idealised C 2h symmetry. [1] Within this the Au(I) centers are linearly coordinated with a Cl-Au-Cl bond angle of 175.0° (close to the ideal value of 180°) and an average bond length of 2.30 Å.
Pages in category "Gold(III) compounds" The following 14 pages are in this category, out of 14 total. This list may not reflect recent changes. C. Chloroauric acid;