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In a photoionization detector, high-energy photons, typically in the vacuum ultraviolet (VUV) range, break molecules into positively charged ions. [2] As compounds enter the detector they are bombarded by high-energy UV photons and are ionized when they absorb the UV light, resulting in ejection of electrons and the formation of positively charged ions.
On the one hand, the ionization energy (also called ionization potential, IP), refers to the energy necessary to remove one electron from a molecule; the lowest IP, corresponding to the ejection of a first electron, is the most biologically relevant factor. On the other hand, the photoionization quantum yield Φ, that is the number of electrons ...
When either the laser intensity is further increased or a longer wavelength is applied as compared with the regime in which multi-photon ionization takes place, a quasi-stationary approach can be used and results in the distortion of the atomic potential in such a way that only a relatively low and narrow barrier between a bound state and the continuum states remains.
Photobiology is the scientific study of the beneficial and harmful interactions of light (technically, non-ionizing radiation) in living organisms. [1] The field includes the study of photophysics, photochemistry, photosynthesis, photomorphogenesis, visual processing, circadian rhythms, photomovement, bioluminescence, and ultraviolet radiation effects.
Appearance energy (also known as appearance potential) is the minimum energy that must be supplied to a gas phase atom or molecule in order to produce an ion. In mass spectrometry, it is accounted as the voltage to correspond for electron ionization. [1] This is the minimum electron energy that produces an ion. [2]
Molecules are ionized using a vacuum ultraviolet (VUV) light source operating at atmospheric pressure (105 Pa), either by direct absorption followed by electron ejection or through ionization of a dopant molecule that leads to chemical ionization of target molecules. The sample is usually a solvent spray that is vaporized by nebulization and heat.
The electron donating power of a donor molecule is measured by its ionization potential, which is the energy required to remove an electron from the highest occupied molecular orbital . The overall energy balance (ΔE), i.e., energy gained or lost, in an electron donor-acceptor transfer is determined by the difference between the acceptor's ...
The high temperature of the plasma is sufficient to cause a very large portion of the sample to form ions. This fraction of ionization can approach 100% for some elements (e.g. sodium), but this is dependent on the ionization potential. A fraction of the formed ions passes through a ~1 mm hole (sampler cone) and then a ~0.4 mm hole (skimmer cone).