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The NaOH (caustic soda) and elevated temperature cause Fe 3 O 4 (black oxide) to form on the surface of the metal instead of Fe 2 O 3 (red oxide; rust). While it is physically denser than red oxide, the fresh black oxide is porous, so oil is then applied as post treatment to the heated part, which seals it by "sinking" into it.
Black oxide provides minimal protection against corrosion, unless also treated with a water-displacing oil to reduce wetting and galvanic action. In colloquial use, thin coatings of black oxide are often termed "gun bluing", while heavier coatings are termed "black oxide". Both refer to the same chemical process for providing true gun bluing. [1]
Tannic acid chemically converts the reddish iron oxides into bluish-black ferric tannate, a more stable material. [2] The second active ingredient is an organic solvent such as 2-butoxyethanol (ethylene glycol monobutyl ether, trade name butyl cellosolve) that acts as a wetting agent and provides a protective primer layer in conjunction with an ...
Mill scale is a complex oxide that contains around 70% iron with traces of nonferrous metals and alkaline compounds. Reduced iron powder may be obtained by conversion of mill scale into a single highest oxide i.e. hematite (Fe 2 O 3) followed by reduction with hydrogen.
A conversion coating is a chemical or electro-chemical treatment applied to manufactured parts that superficially converts the material into a thin adhering coating of an insoluble compound. These coatings are commonly applied to protect the part against corrosion , to improve the adherence of other coatings, for lubrication , or for aesthetic ...
The layer is strongly adherent to the metal surface, and it will regrow quickly if scratched off. In conventional anodizing, this layer of oxide is grown on the surface of the metal by the application of electrical potential, while the part is immersed in an acidic electrolyte. In plasma electrolytic oxidation, higher potentials are applied ...
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