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Most of the ozone production occurs in the tropical upper stratosphere and mesosphere. The total mass of ozone produced per day over the globe is about 400 million metric tons. The global mass of ozone is relatively constant at about 3 billion metric tons, meaning the Sun produces about 12% of the ozone layer each day. [1]
Essentially all UVC (100–280 nm) is blocked by dioxygen (at 100–200 nm) or by ozone (at 200–280 nm) in the atmosphere. The shorter portion of this band and even more energetic UV causes the formation of the ozone layer, when single oxygen atoms produced by UV photolysis of dioxygen (below 240 nm) react with more dioxygen. The ozone layer ...
Ground-level ozone (O 3), also known as surface-level ozone and tropospheric ozone, is a trace gas in the troposphere (the lowest level of the Earth's atmosphere), with an average concentration of 20–30 parts per billion by volume (ppbv), with close to 100 ppbv in polluted areas.
This equation shows how production of ozone is directly related to the solar intensity, and hence to the zenith angle, due to the reliance on photolysis of NO 2. The yield of ozone will therefore be greatest during the day, especially at noon and during the summer season.
Equation 4 relates the concentrations of NO x and ozone, and is known as the Leighton relationship. The time τ {\displaystyle \tau } that is needed to reach a steady state among NO x and ozone is dominated by reaction ( 3 ), which reverses reactions ( 1 )+( 2 ):
The mechanism for carbon monoxide poisoning in the context of carboxyhemoglobin formation is widely credited to Claude Bernard whose memoirs beginning in 1846 and published in 1857 notably phrased, "prevents arterials blood from becoming venous". [4] Felix Hoppe-Seyler independently published similar conclusions in the following year.
Triatomic oxygen (ozone, O 3) is a very reactive allotrope of oxygen that is a pale blue gas at standard temperature and pressure. Liquid and solid O 3 have a deeper blue color than ordinary O 2, and they are unstable and explosive. [5] [6] In its gas phase, ozone is destructive to materials like rubber and fabric and is damaging to lung tissue ...
Since hydroxyl radical is formed during the formation of NO 2, the balance of the sequence of chemical reactions starting with carbon monoxide and leading to the formation of ozone is: CO + 2O 2 + hν → CO 2 + O 3 (where hν refers to the photon of light absorbed by the NO 2 molecule in the sequence)