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John Stewart MacArthur developed the cyanide process for gold extraction in 1887. The expansion of gold mining in the Rand of South Africa began to slow down in the 1880s, as the new deposits found tended to contain pyritic ore. The gold could not be extracted from this compound with any of the then available chemical processes or technologies. [5]
It is the binary cyanide of gold(I). It is an odourless, tasteless yellow solid. [4] Wet gold(I) cyanide is unstable to light and will become greenish. [4] Gold(I) cyanide itself is only of academic interest, but its derivative dicyanoaurate is an intermediate in gold cyanidation, the extraction of gold from its ores. [5]
In gold mining, KCN forms the water-soluble salt potassium gold cyanide (or gold potassium cyanide) and potassium hydroxide from gold metal in the presence of oxygen (usually from the surrounding air) and water: 4 Au + 8 KCN + O 2 + 2 H 2 O → 4 K[Au(CN) 2] + 4 KOH. A similar process uses NaCN to produce sodium gold cyanide (NaAu(CN 2)).
Potassium dicyanoaurate (or potassium gold cyanide) is an inorganic compound with formula K[Au 2]. It is a colorless to white solid that is soluble in water and slightly soluble in alcohol. The salt itself is often not isolated, but solutions of the dicyanoaurate ion ([Au(CN) 2] −) are generated on a large scale in the extraction of gold from ...
Cyanide leaching "heap" at a gold mining operation near Elko, Nevada. On top of the large mounds of ore, are sprinklers dispensing a solution of cyanide. Gold extraction is the extraction of gold from dilute ores using a combination of chemical processes. Gold mining produces about 3600 tons annually, [1] and another 300 tons is produced from ...
KAg(CN) 2 is significant adventitious product of gold mining using cyanide as an extractant. [1] It can be used in silver plating, as a bactericide, and in the manufacture of antiseptics. [2] It forms a variety of coordination polymers, a property that exploits the bridging tendency of the cyanide ligand. [3]
The reaction with hydrochloric acid is an equilibrium reaction that favors formation of tetrachloroaurate(III) anions. This results in a removal of gold ions from solution and allows further oxidation of gold to take place. The gold dissolves to become chloroauric acid. In addition, gold may be dissolved by the chlorine present in aqua regia.
Gold pentafluoride, along with its derivative anion, AuF − 6, and its difluorine complex, gold heptafluoride, is the sole example of gold(V), the highest verified oxidation state. [ 19 ] Some gold compounds exhibit aurophilic bonding , which describes the tendency of gold ions to interact at distances that are too long to be a conventional Au ...