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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Aqueous carbon dioxide reacts with water to form carbonic acid which is very unstable and will dissociate rapidly into hydronium and bicarbonate. Therefore, in seawater, dissolved inorganic carbon is commonly referred to as the collection of bicarbonate, carbonate ions, and dissolved carbon dioxide (CO 2, H 2 CO 3, HCO − 3, CO 2− 3).
Due to the increase in concentration of H + ions from the added HCl, the equilibrium of the dissociation of H 2 S shifts to the left and keeps the value of K a constant. Thus the dissociation of H 2 S decreases, the concentration of un-ionized H 2 S increases, and as a result, the concentration of sulfide ions decreases.
Sodium hydroxide can form several hydrates NaOH·nH 2 O, which result in a complex solubility diagram that was described in detail by Spencer Umfreville Pickering in 1893. [18] The known hydrates and the approximate ranges of temperature and concentration (mass percent of NaOH) of their saturated water solutions are: [13]
This simple model predicts activities of many species (dissolved undissociated gases such as CO 2, H 2 S, NH 3, undissociated acids and bases) to high ionic strengths (up to 5 mol/kg). The value of the constant b for CO 2 is 0.11 at 10 °C and 0.20 at 330 °C. [27] For water as solvent, the activity a w can be calculated using: [26]
The value of each log D is then determined as the logarithm of a ratio—of the sum of the experimentally measured concentrations of the solute's various forms in one solvent, to the sum of such concentrations of its forms in the other solvent; it can be expressed as [10]: 275–8
The value of the enthalpy of solvation is the sum of these individual steps: = +. Dissolving ammonium nitrate in water is endothermic. The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules.
‡ Dissolved CO 2 volume per volume H 2 O: grams CO 2 per 100 ml H 2 O: 18 °C: 0.928: 0.1789 19 °C: ... Carbon dioxide liquid/vapor equilibrium thermodynamic data ...