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The Wijs solution, iodine monochloride dissolved in acetic acid, is used to determine the iodine value of a substance. It can also be used to prepare iodates, by reaction with a chlorate. Chlorine is released as a byproduct. Iodine monochloride is a Lewis acid that forms 1:1 adducts with Lewis bases such as dimethylacetamide and benzene.
These iodine compounds are hypervalent because the iodine atom formally contains in its valence shell more than the 8 electrons required for the octet rule. Hypervalent iodine oxyanions are known for oxidation states +1, +3, +5, and +7; organic analogues of these moieties are known for each oxidation state except +7.
This is an accepted version of this page This is the latest accepted revision, reviewed on 25 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
Iodine trichloride, which exists in the solid state as the planar dimer I 2 Cl 6, is a bright yellow solid, synthesised by reacting iodine with liquid chlorine at −80 °C; caution is necessary during purification because it easily dissociates to iodine monochloride and chlorine and hence can act as a strong chlorinating agent.
For example, Iodotyrosine deiodinase is a mammalian enzyme with the unusual function of aerobic reductive dehalogenation of iodine- or bromine-substituted organic substrates. [6] Bromoxynil and ioxynil herbicides have been shown to undergo a variety of environmental transformations, including reductive dehalogenation by anaerobic bacteria.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Iodine chloride may refer to: Iodine monochloride, ICl; Iodine dichloride, ICl 2 ...
Such a triglyceride has a high iodine value (approx. 119). Below, the reaction product after the addition of four equivalents of iodine or bromine to the four C=C double bonds of the unsaturated fatty acid residues. The determination of iodine value is a particular example of iodometry. A solution of iodine I 2 is yellow/brown in color.