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For weak electrolytes (i.e. incompletely dissociated electrolytes), however, the molar conductivity strongly depends on concentration: The more dilute a solution, the greater its molar conductivity, due to increased ionic dissociation. For example, acetic acid has a higher molar conductivity in dilute aqueous acetic acid than in concentrated ...
Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. [1] For example, the measurement of product conductivity is a typical way to monitor and continuously trend the performance of water purification systems.
λ is the thermal conductivity, ρ is the density, D im is the mixture-averaged diffusion coefficient, c p is the specific heat capacity at constant pressure. In the field of fluid mechanics, many sources define the Lewis number to be the inverse of the above definition. [3] [4]
In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric titration while the term conductimetry is used to describe non-titrative applications. [1] Conductometry is often applied to determine the total conductance of a solution or to analyze the end point of titrations that include ions. [2]
An acid-base indicator such as bromophenol blue is added to make visible the boundary between the acidic HCl solution and the near-neutral CdCl 2 solution. [8] The boundary tends to remain sharp since the leading solution HCl has a higher conductivity that the indicator solution CdCl 2 , and therefore a lower electric field to carry the same ...
The conductivity of a water/aqueous solution is highly dependent on its concentration of dissolved salts, and other chemical species that ionize in the solution. Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher ...
The Ostwald law of dilution provides a satisfactory description of the concentration dependence of the conductivity of weak electrolytes like CH 3 COOH and NH 4 OH. [3] [4] The variation of molar conductivity is essentially due to the incomplete dissociation of weak electrolytes into ions.
Since metals can display multiple oxidation numbers, the exact definition of how many "valence electrons" an element should have in elemental form is somewhat arbitrary, but the following table lists the free electron densities given in Ashcroft and Mermin, which were calculated using the formula above based on reasonable assumptions about ...