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Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a solution. [1] For example, the measurement of product conductivity is a typical way to monitor and continuously trend the performance of water purification systems.
For weak electrolytes (i.e. incompletely dissociated electrolytes), however, the molar conductivity strongly depends on concentration: The more dilute a solution, the greater its molar conductivity, due to increased ionic dissociation. For example, acetic acid has a higher molar conductivity in dilute aqueous acetic acid than in concentrated ...
The conductivity of a water/aqueous solution is highly dependent on its concentration of dissolved salts, and other chemical species that ionize in the solution. Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher ...
For example, in an aqueous solution of sodium chloride, less than half of the current is carried by the positively charged sodium ions (cations) and more than half is carried by the negatively charged chloride ions (anions) because the chloride ions are able to move faster, i.e., chloride ions have higher mobility than sodium ions. The sum of ...
In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric titration while the term conductimetry is used to describe non-titrative applications. [1] Conductometry is often applied to determine the total conductance of a solution or to analyze the end point of titrations that include ions. [2]
Degas conductivity is used as an indicator of water quality in the water/steam cycle of power stations. Excessive conductivity values often indicate high corrosion potential, especially with certain ions such as chloride and acetate ions. These can be particularly damaging to the blades in the steam turbine.
In this case, the carrier density (in this context, also called the free electron density) can be estimated by: [5] n = N A Z ρ m m a {\displaystyle n={\frac {N_{\text{A}}Z\rho _{m}}{m_{a}}}} Where N A {\displaystyle N_{\text{A}}} is the Avogadro constant , Z is the number of valence electrons , ρ m {\displaystyle \rho _{m}} is the density of ...
Chapman–Enskog theory provides a framework in which equations of hydrodynamics for a gas can be derived from the Boltzmann equation.The technique justifies the otherwise phenomenological constitutive relations appearing in hydrodynamical descriptions such as the Navier–Stokes equations.