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This is accomplished by solving heat equations in both regions, subject to given boundary and initial conditions. At the interface between the phases (in the classical problem) the temperature is set to the phase change temperature. To close the mathematical system a further equation, the Stefan condition, is required. This is an energy balance ...
When the phase change occurs, there is a "thermal arrest"; that is, the temperature stays constant. This is because the matter has more internal energy as a liquid or gas than in the state that it is cooling to. The amount of energy required for a phase change is known as latent heat. The "cooling rate" is the slope of the cooling curve at any ...
Computational Fluid Dynamics (CFD) modeling and simulation for phase change materials (PCMs) is a technique used to analyze the performance and behavior of PCMs. The CFD models have been successful in studying and analyzing the air quality, natural ventilation and stratified ventilation, air flow initiated by buoyancy forces and temperature space for the systems integrated with PCMs.
As seen in the heat equation, [5] =, one way to view thermal diffusivity is as the ratio of the time derivative of temperature to its curvature, quantifying the rate at which temperature concavity is "smoothed out". In a substance with high thermal diffusivity, heat moves rapidly through it because the substance conducts heat quickly relative ...
However, if the specific heat changes, the LMTD approach will no longer be accurate. A particular case for the LMTD are condensers and reboilers, where the latent heat associated to phase change is a special case of the hypothesis. For a condenser, the hot fluid inlet temperature is then equivalent to the hot fluid exit temperature.
A phase-change material (PCM) is a substance which releases/absorbs sufficient energy at phase transition to provide useful heat or cooling. Generally the transition will be from one of the first two fundamental states of matter - solid and liquid - to the other.
Phase-field models are usually constructed in order to reproduce a given interfacial dynamics. For instance, in solidification problems the front dynamics is given by a diffusion equation for either concentration or temperature in the bulk and some boundary conditions at the interface (a local equilibrium condition and a conservation law), [14] which constitutes the sharp interface model.
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125