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ΔY- and YΔ-transformations are a tool both in pure graph theory as well as applications. Both operations preserve a number of natural topological properties of graphs. . For example, applying a YΔ-transformation to a 3-vertex of a planar graph, or a ΔY-transformation to a triangular face of a planar graph, results again in a planar graph.
In chemistry, solvent effects are the influence of a solvent on chemical reactivity or molecular associations. Solvents can have an effect on solubility, stability and reaction rates and choosing the appropriate solvent allows for thermodynamic and kinetic control over a chemical reaction.
A delta-wye transformer is a type of three-phase electric power transformer design that employs delta-connected windings on its primary and wye/star connected windings on its secondary. A neutral wire can be provided on wye output side. It can be a single three-phase transformer, or built from three independent single-phase units. An equivalent ...
In circuit design, the Y-Δ transform, also written wye-delta and also known by many other names, is a mathematical technique to simplify the analysis of an electrical network. The name derives from the shapes of the circuit diagrams , which look respectively like the letter Y and the Greek capital letter Δ .
The silver concentration in the test sample is the x-intercept of the plot. The dilution factor is multiplied by this initial concentration to determine the original concentration. Matrix effects occur even with methods such as plasma spectrometry , which have a reputation for being relatively free from interferences.
The gauche effect is very sensitive to solvent effects, due to the large difference in polarity between the two conformers.For example, 2,3-dinitro-2,3-dimethylbutane, which in the solid state exists only in the gauche conformation, prefers the gauche conformer in benzene solution by a ratio of 79:21, but in carbon tetrachloride, it prefers the anti conformer by a ratio of 58:42. [9]
Bonding between molecules is more subtle than the three parameters suggest. Molecular shape is relevant, as are other types of bonding such as induced dipole, metallic and electrostatic interactions. The size of the molecules also plays a significant role in whether two molecules actually dissolve in a given period.
Nitric oxide is an even stronger π-acceptor than CO and ν NO is a diagnostic tool in metal–nitrosyl chemistry. Isocyanides , RNC, are another class of ligands that are capable of π-backbonding. In contrast with CO, the σ-donor lone pair on the C atom of isocyanides is antibonding in nature and upon complexation the CN bond is strengthened ...