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A Maxwell material is the most simple model viscoelastic material showing properties of a typical liquid. It shows viscous flow on the long timescale, but additional elastic resistance to fast deformations. [1] It is named for James Clerk Maxwell who proposed the model in 1867. [2] [3] It is also known as a Maxwell fluid
The generalized Maxwell model, also known as the Wiechert model, is the most general form of the linear model for viscoelasticity. It takes into account that the relaxation does not occur at a single time, but at a distribution of times. Due to molecular segments of different lengths with shorter ones contributing less than longer ones, there ...
Experimentally, stress relaxation is determined by step strain experiments, i.e. by applying a sudden one-time strain and measuring the build-up and subsequent relaxation of stress in the material (see figure), in either extensional or shear rheology. a) Applied step strain and b) induced stress as functions of time for a viscoelastic material.
Often, the simpler Maxwell model and the Kelvin–Voigt model are used. These models often prove insufficient, however; the Maxwell model does not describe creep or recovery, and the Kelvin–Voigt model does not describe stress relaxation. SLS is the simplest model that predicts both phenomena.
For this case only two components of the shear stress became non-zero: = ˙ and = ˙ where ˙ is the shear rate.. Thus, the upper-convected Maxwell model predicts for the simple shear that shear stress to be proportional to the shear rate and the first difference of normal stresses is proportional to the square of the shear rate, the second difference of normal stresses is always zero.
The generalized Maxwell model also known as the Maxwell–Wiechert model (after James Clerk Maxwell and E Wiechert [1] [2]) is the most general form of the linear model for viscoelasticity. In this model, several Maxwell elements are assembled in parallel. It takes into account that the relaxation does not occur at a single time, but in a set ...
Vibrational energy relaxation, or vibrational population relaxation, is a process in which the population distribution of molecules in quantum states of high energy level caused by an external perturbation returns to the Maxwell–Boltzmann distribution. In solution, the process proceeds with intra- and intermolecular energy transfer. The ...
Equivalently, the relaxation time is the time required for the stress induced, by a suddenly applied reference strain, to reduce by a certain reference amount. The relaxation time is actually based on the rate of relaxation that exists at the moment of the suddenly applied load. This incorporates both the elasticity and viscosity of the material.