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The molar volume of gases around STP and at atmospheric pressure can be calculated with an accuracy that is usually sufficient by using the ideal gas law. The molar volume of any ideal gas may be calculated at various standard reference conditions as shown below: V m = 8.3145 × 273.15 / 101.325 = 22.414 dm 3 /mol at 0 °C and 101.325 kPa
For example, Paraffin has very large molecules and thus a high heat capacity per mole, but as a substance it does not have remarkable heat capacity in terms of volume, mass, or atom-mol (which is just 1.41 R per mole of atoms, or less than half of most solids, in terms of heat capacity per atom).
In that case, the specific volume would equal 0.4672 in 3 /lb. However, if the temperature is changed to 1160 °R, the specific volume of the super heated steam would have changed to 0.2765 in 3 /lb, which is a 59% overall change. Knowing the specific volumes of two or more substances allows one to find useful information for certain applications.
Gas undergoes a slight expansion when the temperature is raised from 15 °C (59 °F) to 60 °F and this expansion is built into the above factor for gas. The standard temperature and pressure (STP) for gas varies depending on the particular code being used. [2] It is just as important to know the standard pressure as the temperature.
One example of standard conditions for the calculation of SCCM is = 0 °C (273.15 K) [1] and = 1.01 bar (14.72 psia) and a unity compressibility factor = 1 (i.e., an ideal gas is used for the definition of SCCM). [2] This example is for the semi-conductor-manufacturing industry.
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
Gives 1.1981 moles per scf or 0.002641 pound moles per scf. The standard cubic meter of gas (scm) is used in the context of the SI system. It is similarly defined as the quantity of gas contained in a cubic meter at a temperature of 15 °C (288.150 K; 59.000 °F) and a pressure of 101.325 kilopascals (1.0000 atm; 14.696 psi). [1]
When positive pressure is applied to a standard cubic foot of gas, it is compressed. When a vacuum is applied to a standard cubic foot of gas, it expands. The volume of gas after it is pressurized or rarefied is referred to as its "actual" volume. SCF and ACF for an ideal gas are related in accordance with the combined gas law: [2] [3]