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Living polymerization: A chain polymerization from which chain transfer and chain termination are absent. Note : In many cases, the rate of chain initiation is fast compared with the rate of chain propagation, so that the number of kinetic-chain carriers is essentially constant throughout the polymerization.
Living cationic polymerization is a living polymerization technique involving cationic propagating species. [1] [2] It enables the synthesis of very well defined polymers (low molar mass distribution) and of polymers with unusual architecture such as star polymers and block copolymers and living cationic polymerization is therefore as such of commercial and academic interest.
Boris Karloff in James Whale's 1931 film Frankenstein, based on Mary Shelley's 1818 novel.The monster is created by an unorthodox biology experiment.. Biology appears in fiction, especially but not only in science fiction, both in the shape of real aspects of the science, used as themes or plot devices, and in the form of fictional elements, whether fictional extensions or applications of ...
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. [1] [2] [3] There are many forms of polymerization [4] and different systems exist to categorize them. IUPAC definition for ...
Living free radical polymerization is a type of living polymerization where the active polymer chain end is a free radical. Several methods exist. Several methods exist. IUPAC recommends [ 1 ] to use the term " reversible-deactivation radical polymerization " instead of "living free radical polymerization", though the two terms are not synonymous.
A wheeled buffalo figurine—probably a children's toy—from Magna Graecia in archaic Greece [1]. Several organisms are capable of rolling locomotion. However, true wheels and propellers—despite their utility in human vehicles—do not play a significant role in the movement of living things (with the exception of the corkscrew-like flagella of many prokaryotes).
Dragon's Egg is a 1980 hard science fiction novel by American writer Robert L. Forward.In the story, Dragon's Egg is a neutron star with a surface gravity 67 billion times that of Earth, and inhabited by cheela, intelligent creatures the size of sesame seeds who evolve, live, and think a million times faster than humans.
Recently one example of chain-growth supramolecular polymerization with "living" characteristics is demonstrated. [21] In this case, a bowl-shaped monomer with amide-appended side chains form a kinetically favored intramolecular hydrogen bonding network and does not spontaneously undergo supramolecular polymerization at ambient temperatures. [ 22 ]