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Curium(III) oxide is a compound composed of curium and oxygen with the chemical formula Cm 2 O 3. It is a crystalline solid with a unit cell that contains two curium atoms and three oxygen atoms. The simplest synthesis equation involves the reaction of curium(III) metal with O 2−: 2 Cm 3+ + 3 O 2−---> Cm 2 O 3. [1]
Metallic curium is annealed in air or in an oxygen atmosphere: [1] Cm + O 2 → CmO 2. Curium(III) hydroxide and curium(III) oxalate are also usually used for this purpose: Cm(OH) 4 → CmO 2 + 2H 2 O Cm(C 2 O 4) 2 → CmO 2 + 2CO 2 + 2CO. Another way is the reaction of curium(III) oxide in an oxygen atmosphere at 650 °C: [2] 2Cm 2 O 3 + O 2 ...
Curium readily reacts with oxygen forming mostly Cm 2 O 3 and CmO 2 oxides, [1] but the divalent oxide CmO is also known. [2] Black CmO 2 can be obtained by burning curium oxalate (Cm 2 (C 2 O 4) 3), nitrate (Cm(NO 3) 3), or hydroxide in pure oxygen. [3] [4] Upon heating to 600–650 °C in vacuum (about 0.01 Pa), it transforms into the whitish ...
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
The Ellingham diagram plots the Gibbs free energy change (ΔG) for each oxidation reaction as a function of temperature. For comparison of different reactions, all values of ΔG refer to the reaction of the same quantity of oxygen, chosen as one mole O (1 ⁄ 2 mol O 2) by some authors [2] and one mole O 2 by others. [3] The diagram shown ...
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All isotopes ranging from 242 Cm to 248 Cm, as well as 250 Cm, undergo a self-sustaining nuclear chain reaction and thus in principle can be a nuclear fuel in a reactor. As in most transuranic elements, nuclear fission cross section is especially high for the odd-mass curium isotopes 243 Cm, 245 Cm and 247 Cm.
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