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Curium(III) oxide is a compound composed of curium and oxygen with the chemical formula Cm 2 O 3. It is a crystalline solid with a unit cell that contains two curium atoms and three oxygen atoms. The simplest synthesis equation involves the reaction of curium(III) metal with O 2− : 2 Cm 3+ + 3 O 2− ---> Cm 2 O 3 . [ 1 ]
Metallic curium is annealed in air or in an oxygen atmosphere: [1] Cm + O 2 → CmO 2. Curium(III) hydroxide and curium(III) oxalate are also usually used for this purpose: Cm(OH) 4 → CmO 2 + 2H 2 O Cm(C 2 O 4) 2 → CmO 2 + 2CO 2 + 2CO. Another way is the reaction of curium(III) oxide in an oxygen atmosphere at 650 °C: [2] 2Cm 2 O 3 + O 2 ...
Curium readily reacts with oxygen forming mostly Cm 2 O 3 and CmO 2 oxides, [1] but the divalent oxide CmO is also known. [2] Black CmO 2 can be obtained by burning curium oxalate (Cm 2 (C 2 O 4) 3), nitrate (Cm(NO 3) 3), or hydroxide in pure oxygen. [3] [4] Upon heating to 600–650 °C in vacuum (about 0.01 Pa), it transforms into the whitish ...
Curium readily reacts with oxygen forming mostly Cm 2 O 3 and CmO 2 oxides, [53] but the divalent oxide CmO is also known. [67] Black CmO 2 can be obtained by burning curium oxalate (Cm 2 (C 2 O 4) 3), nitrate (Cm(NO 3) 3), or hydroxide in pure oxygen. [29] [68] Upon heating to 600–650 °C in vacuum (about 0.01 Pa), it transforms into the ...
A chemical equation is the symbolic representation of a chemical reaction in the form of symbols and chemical formulas.The reactant entities are given on the left-hand side and the product entities are on the right-hand side with a plus sign between the entities in both the reactants and the products, and an arrow that points towards the products to show the direction of the reaction. [1]
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The main disadvantage of the stoichiometric ceria cycle lies in the fact that the reduction reaction temperature of cerium(IV) oxide is at the same range of the melting temperature (1,687–2,230 °C) of cerium(IV) oxide (), [5] which in the end results in some melting and sublimation of the material, which can produce reactor failures such as ...
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