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The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
The ideal gas law can also be derived from first principles using the kinetic theory of gases, in which several simplifying assumptions are made, chief among which are that the molecules, or atoms, of the gas are point masses, possessing mass but no significant volume, and undergo only elastic collisions with each other and the sides of the ...
In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The specific volume, an intensive property, is the system's volume per unit mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature.
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
The other equation of state of an ideal gas must express Joule's second law, that the internal energy of a fixed mass of ideal gas is a function only of its temperature, with = (,). For the present purposes it is convenient to postulate an exemplary version of this law by writing:
The equation shows that, as the number of moles of gas increases, the volume of the gas also increases in proportion. Similarly, if the number of moles of gas is decreased, then the volume also decreases. Thus, the number of molecules or atoms in a specific volume of ideal gas is independent of their size or the molar mass of the gas.
If one sets out to determine the specific volume of an ideal gas, such as super heated steam, using the equation ν = RT/P, where pressure is 2500 lbf/in 2, R is 0.596, temperature is 1960 °R. In that case, the specific volume would equal 0.4672 in 3 /lb.
Specific volume is an example of an intensive property because it is the ratio of volume occupied by a unit of mass of a gas that is identical throughout a system at equilibrium. [ 17 ] 1000 atoms a gas occupy the same space as any other 1000 atoms for any given temperature and pressure.