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An ubiquitous example of a hydrogen bond is found between water molecules. In a discrete water molecule, there are two hydrogen atoms and one oxygen atom. The simplest case is a pair of water molecules with one hydrogen bond between them, which is called the water dimer and is often used as a model system. When more molecules are present, as is ...
Water (H. 2O) is a simple triatomic bent molecule with C 2v molecular symmetry and bond angle of 104.5° between the central oxygen atom and the hydrogen atoms. Despite being one of the simplest triatomic molecules, its chemical bonding scheme is nonetheless complex as many of its bonding properties such as bond angle, ionization energy, and ...
Although hydrogen bonding is a relatively weak attraction compared to the covalent bonds within the water molecule itself, it is responsible for several of the water's physical properties. These properties include its relatively high melting and boiling point temperatures: more energy is required to break the hydrogen bonds between water molecules.
Model of hydrogen bonds (1) between molecules of water. Because of its polarity, a molecule of water in the liquid or solid state can form up to four hydrogen bonds with neighboring molecules. Hydrogen bonds are about ten times as strong as the Van der Waals force that attracts molecules to each other
For example, the water molecule (H 2 O) contains two polar O−H bonds in a bent (nonlinear) geometry. The bond dipole moments do not cancel, so that the molecule forms a molecular dipole with its negative pole at the oxygen and its positive pole midway between the two hydrogen atoms. In the figure each bond joins the central O atom with a ...
Water cluster. Hypothetical (H 2 O) 100 icosahedral water cluster and the underlying structure. In chemistry, a water cluster is a discrete hydrogen bonded assembly or cluster of molecules of water. [1][2] Many such clusters have been predicted by theoretical models (in silico), and some have been detected experimentally in various contexts ...
In liquid water the rotational transitions are effectively quenched, but absorption bands are affected by hydrogen bonding. In crystalline ice the vibrational spectrum is also affected by hydrogen bonding and there are lattice vibrations causing absorption in the far-infrared. Electronic transitions of gaseous molecules will show both ...
The water dimer consists of two water molecules loosely bound by a hydrogen bond. It is the smallest water cluster. Because it is the simplest model system for studying hydrogen bonding in water, it has been the target of many theoretical [1][2][3] (and later experimental) studies that it has been called a "theoretical Guinea pig". [4]