Search results
Results From The WOW.Com Content Network
Phthalic anhydride is produced similarly by V 2 O 5-catalysed oxidation of ortho-xylene or naphthalene at 350–400 °C. The equation for the vanadium oxide-catalysed oxidation of o-xylene to phthalic anhydride: C 6 H 4 (CH 3) 2 + 3 O 2 → C 6 H 4 (CO) 2 O + 3 H 2 O. The equation for the vanadium oxide-catalysed oxidation of naphthalene to ...
In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium , most of which exist in its highest oxidation state of +5. The complexes [V(CN) 6 ] 3− and [V 2 Cl 9 ] 3− are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively.
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. Conceptually, the oxidation state may be positive, negative or zero.
From left: [V(H 2 O) 6] 2+ (lilac), [V(H 2 O) 6] 3+ (green), [VO(H 2 O) 5] 2+ (blue) and [VO(H 2 O) 5] 3+ (yellow).. Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to ...
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2.It is a dark blue solid. Vanadium(IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO] 2+ and in alkali to give the brown [V 4 O 9] 2− ion, or at high pH [VO 4] 4−. [4]
The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5. In an aqueous solution , vanadium forms metal aquo complexes of which the colors are lilac [V(H 2 O) 6 ] 2+ , green [V(H 2 O) 6 ] 3+ , blue [VO(H 2 O) 5 ] 2+ , yellow-orange oxides [VO(H 2 O) 5 ] 3+ , the formula for which depends on pH.
This equation is the equation of a straight line for as a function of pH with a slope of () volt (pH has no units). This equation predicts lower E h {\displaystyle E_{h}} at higher pH values. This is observed for the reduction of O 2 into H 2 O, or OH − , and for reduction of H + into H 2 .
Vanadyl sulfate is most commonly obtained by reduction of vanadium pentoxide with sulfur dioxide: . V 2 O 5 + 7 H 2 O + SO 2 + H 2 SO 4 → 2 [V(O)(H 2 O) 4]SO 4. From aqueous solution, the salt crystallizes as the pentahydrate, the fifth water is not bound to the metal in the solid.