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  2. Superbase - Wikipedia

    en.wikipedia.org/wiki/Superbase

    Caubère defines superbases as "bases resulting from a mixing of two (or more) bases leading to new basic species possessing inherent new properties. The term superbase does not mean a base is thermodynamically and/or kinetically stronger than another, instead it means that a basic reagent is created by combining the characteristics of several ...

  3. ECW model - Wikipedia

    en.wikipedia.org/wiki/ECW_Model

    In chemistry, the ECW model is a semi-quantitative model that describes and predicts the strength of Lewis acid–Lewis base interactions. Many chemical reactions can be described as acid–base reactions, so models for such interactions are of potentially broad interest.

  4. Base (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Base_(chemistry)

    A strong base is a basic chemical compound that can remove a proton (H +) from (or deprotonate) a molecule of even a very weak acid (such as water) in an acid–base reaction. Common examples of strong bases include hydroxides of alkali metals and alkaline earth metals, like NaOH and Ca(OH) 2, respectively. Due to their low solubility, some ...

  5. List of unsolved problems in chemistry - Wikipedia

    en.wikipedia.org/wiki/List_of_unsolved_problems...

    RNA folding problem: Is it possible to accurately predict the secondary, tertiary and quaternary structure of a polyribonucleic acid sequence based on its sequence and environment? Protein design : Is it possible to design highly active enzymes de novo for any desired reaction?

  6. HSAB theory - Wikipedia

    en.wikipedia.org/wiki/HSAB_theory

    HSAB is an acronym for "hard and soft (Lewis) acids and bases".HSAB is widely used in chemistry for explaining the stability of compounds, reaction mechanisms and pathways. It assigns the terms 'hard' or 'soft', and 'acid' or 'base' to chemical species.

  7. Lewis acids and bases - Wikipedia

    en.wikipedia.org/wiki/Lewis_acids_and_bases

    As usual, a weaker acid has a stronger conjugate base. Examples of Lewis bases based on the general definition of electron pair donor include: simple anions, such as H − and F −; other lone-pair-containing species, such as H 2 O, NH 3, HO −, and CH 3 −; complex anions, such as sulfate; electron-rich π-system Lewis bases, such as ethyne ...

  8. Frustrated Lewis pair - Wikipedia

    en.wikipedia.org/wiki/Frustrated_Lewis_pair

    Intermolecular FLPs are where the Lewis base is a separate molecule to the Lewis acid, it is thought that these individual molecules interact through secondary London dispersion interactions to bring the Lewis base and acid together (a pre-organisational effect) where small molecules may then interact with the FLPs.

  9. Pauling's rules - Wikipedia

    en.wikipedia.org/wiki/Pauling's_rules

    One of Pauling's examples is olivine, M 2 SiO 4, where M is a mixture of Mg 2+ at some sites and Fe 2+ at others. The structure contains distinct SiO 4 tetrahedra which do not share any oxygens (at corners, edges or faces) with each other. The lower-valence Mg 2+ and Fe 2+ cations are surrounded by polyhedra which do share oxygens.