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Caprolactam (CPL) is an organic compound with the formula (CH 2) 5 C(O)NH. This colourless solid is a lactam (a cyclic amide ) of caproic acid . Global demand for this compound is approximately five million tons per year, and the vast majority is used to make Nylon 6 filament, fiber, and plastics.
Caprolactam molecule used to synthesize Nylon 6 by ring opening polymerization. Nylon 6 or polycaprolactam is a polymer, in particular semicrystalline polyamide.Unlike most other nylons, nylon 6 is not a condensation polymer, but instead is formed by ring-opening polymerization; this makes it a special case in the comparison between condensation and addition polymers.
Although no longer economical, caprolactone was once produced as a precursor to caprolactam. Caprolactone is treated with ammonia at elevated temperatures to give the lactam: (CH 2) 5 CO 2 + NH 3 → (CH 2) 5 C(O)NH + H 2 O. Carbonylation of caprolactone gives, after hydrolysis, pimelic acid. The lactone ring is easily opened with nucleophiles ...
The monomers can be amides themselves (usually in the form of a cyclic lactam such as caprolactam), α,ω-amino acids or a stoichiometric mixture of a diamine and a diacid. Both these kinds of precursors give a homopolymer. Polyamides are easily copolymerized, and thus many mixtures of monomers are possible which can in turn lead to many ...
Their common names are β-propiolactam, γ-butyrolactam, δ-valerolactam, and ε-caprolactam. A lactam is a cyclic amide, formally derived from an amino alkanoic acid through cyclization reactions. The term is a portmanteau of the words lactone + amide.
PCL beads, as sold for industrial or hobbyist use. Polycaprolactone (PCL) is a synthetic, semi-crystalline, biodegradable polyester with a melting point of about 60 °C and a glass transition temperature of about −60 °C.
For this reason it is effective in treatment of certain bleeding disorders, and it is sold under the brand name Amicar. [3] Aminocaproic acid is also an intermediate in the polymerization of Nylon-6, where it is formed by ring-opening hydrolysis of caprolactam. The crystal structure determination showed that the 6-aminohexanoic acid is present ...
A polymerization in which a cyclic monomer yields a monomeric unit which is acyclic or contains fewer cycles than the monomer. Note: If monomer is polycyclic, the opening of a single ring is sufficient to classify the reaction as ring-opening polymerization. Modified from the earlier definition. [1] [2]