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Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.
Hydrogen peroxide (H 2 O 2) can be used as HOCl scavenger whose byproducts do not interfere in the Pinnick oxidation reaction: HOCl + H 2 O 2 → HCl + O 2 + H 2 O. In a weakly acidic condition, fairly concentrated (35%) H 2 O 2 solution undergoes a rapid oxidative reaction with no competitive reduction reaction of HClO 2 to form HOCl. HClO 2 ...
The following figure shows the reaction mechanism: [2] Reaktionsmechanismus Albright-Goldman-Oxidation. First, dimethyl sulfoxide (1) reacts with acetic anhydride to form a sulfonium ion. It reacts with the primary alcohol in an addition reaction. Furthermore, acetic acid is cleaved, so that intermediate 2 is formed. The latter reacts upon ...
Similar conditions and catalysts are used for butane oxidation, the oxygen in air to produce acetic acid can oxidize acetaldehyde. [42] 2 CH 3 CHO + O 2 → 2 CH 3 CO 2 H. Using modern catalysts, this reaction can have an acetic acid yield greater than 95%.
Metabolism of ethanol forms acetaldehyde before acetaldehyde dehydrogenase forms acetic acid, but with the enzyme inhibited, acetaldehyde accumulates. If one consumes ethanol while taking disulfiram, the hangover effect of ethanol is felt more rapidly and intensely (disulfiram-alcohol reaction). As such, disulfiram is sometimes used as a ...
Using Lewis acid catalyst (boron trifluoride) or strong organic acids (trifluoroacetic acid) in chlorinated solvents, yields improved to 30-40%. [ 9 ] Green chemistry variants have been developed in which the reaction is performed with microwave irradiation using reactants adsorbed on acidic silica gel [ 10 ] or at high temperature in the gas ...
An Oppenauer oxidation of aldehyde. Another side reaction is the Tischenko reaction of aldehyde products with no α-hydrogen, but this can be prevented by use of anhydrous solvents. [4] Another general side reaction is the migration of the double bond during the oxidation of allylic alcohol substrates. [14] Oppenauer oxidation of a steroid ...
Acetogenesis is a process through which acetyl-CoA [1] or acetic acid is produced by anaerobic bacteria through the reduction of CO 2 via the Wood–Ljungdahl pathway.Other microbial processes that produce acetic acid (like certain types of fermentation or the oxidative breakdown of carbohydrates or ethanol by acetic acid bacteria) are not considered acetogenesis.