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Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell .
The term "Maxwell's equations" is often also used for equivalent alternative formulations. Versions of Maxwell's equations based on the electric and magnetic scalar potentials are preferred for explicitly solving the equations as a boundary value problem, analytical mechanics, or for use in quantum mechanics.
Thus, we use more complex relations such as Maxwell relations, the Clapeyron equation, and the Mayer relation. Maxwell relations in thermodynamics are critical because they provide a means of simply measuring the change in properties of pressure, temperature, and specific volume, to determine a change in entropy. Entropy cannot be measured ...
The placement and relation among the variables serves as a key to recall the relations they constitute. A mnemonic used by students to remember the Maxwell relations (in thermodynamics ) is " G ood P hysicists H ave S tudied U nder V ery F ine T eachers", which helps them remember the order of the variables in the square, in clockwise direction.
The Euler relation for a paramagnetic system is then: = + + and the Gibbs-Duhem relation for such a system is: S d T − V d P + I d B e + N d μ = 0 {\displaystyle SdT-VdP+IdB_{e}+Nd\mu =0} An experimental problem that distinguishes magnetic systems from other thermodynamical systems is that the magnetic moment can't be constrained.
Maxwell introduced the term D, specific capacity of electric induction, in a form different from the modern and familiar notations. [3] It was Oliver Heaviside who reformulated the complicated Maxwell's equations to the modern form. It wasn't until 1884 that Heaviside, concurrently with Willard Gibbs and Heinrich Hertz, grouped the equations ...
In fact, Maxwell's equations were crucial in the historical development of special relativity. However, in the usual formulation of Maxwell's equations, their consistency with special relativity is not obvious; it can only be proven by a laborious calculation. For example, consider a conductor moving in the field of a magnet. [8]
One of the early uses of the matrix forms of the Maxwell's equations was to study certain symmetries, and the similarities with the Dirac equation. The matrix form of the Maxwell's equations is used as a candidate for the Photon Wavefunction. [8] Historically, the geometrical optics is based on the Fermat's principle of least time. Geometrical ...