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Beginning in 1908, luminous paint containing a mixture of radium and copper-doped zinc sulfide was used to paint watch faces and instrument dials, giving a greenish glow. Phosphors containing copper-doped zinc sulfide (ZnS:Cu) yield blue-green light; copper and manganese-doped zinc sulfide (ZnS:Cu,Mn), yielding yellow-orange light are also used ...
Although old radium dials generally no longer produce light, this is due to the breakdown of the crystal structure of the luminous zinc sulfide rather than the radioactive decay of the radium. The radium isotope ( 226 Ra ) used has a half-life of about 1,600 years, [ 7 ] so radium dials remain essentially just as radioactive as when originally ...
Radium paint used zinc sulfide phosphor, usually trace metal doped with an activator, such as copper (for green light), silver (blue-green), and more rarely copper-magnesium (for yellow-orange light). The phosphor degrades relatively fast and the dials lose luminosity in several years to a few decades; clocks and other devices available from ...
Radium was used to make self-luminous paint from the early 20th century to about 1970. Promethium briefly replaced radium as a radiation source. Tritium is the only radiation source used in radioluminescent light sources today due to its low radiological toxicity and commercial availability. [3]
The company's luminescent paint, marketed as Undark, was a mixture of radium and zinc sulfide; the radiation causing the sulfide to fluoresce. During World War I, demand for dials, watches, and aircraft instruments painted with Undark surged, and the company expanded operations considerably.
Between 1913 and 1950 radium-228 and radium-226 were used to activate a phosphor made of silver doped zinc sulfide (ZnS:Ag), which gave a greenish glow. The phosphor is not suitable to be used in layers thicker than 25 mg/cm 2 , as the self-absorption of the light then becomes a problem.
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