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The limiting reagent (or limiting reactant or limiting agent) in a chemical reaction is a reactant that is totally consumed when the chemical reaction is completed. [ 1 ] [ 2 ] The amount of product formed is limited by this reagent, since the reaction cannot continue without it.
The limiting reagent is the reagent that limits the amount of product that can be formed and is completely consumed when the reaction is complete. An excess reactant is a reactant that is left over once the reaction has stopped due to the limiting reactant being exhausted.
The limiting reagent determines the theoretical yield—the relative quantity of moles of reactants and the product formed in a chemical reaction. Other reactants are said to be present in excess. The actual yield—the quantity physically obtained from a chemical reaction conducted in a laboratory—is often less than the theoretical yield. [ 8 ]
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
Unlike more common pseudo-first-order analysis, in which an overwhelming excess of one or more reagents is used relative to a species of interest, RPKA probes reactions at synthetically relevant conditions (i.e. with concentrations and reagent ratios resembling those used in the reaction when not exploring the rate law.)
If neither monomer is in excess, then r = 1 and the equation reduces to the equimolar case above. The effect of the excess reactant is to reduce the degree of polymerization for a given value of p. In the limit of complete conversion of the limiting reagent monomer, p → 1 and ¯ +
He was one of the best in baseball history at striking batters out and limiting hard contact. Among all pitchers with at least 900 major league innings, Wagner is No. 1 all-time in BOTH strikeouts ...
The supply of this reagent thus limits the amount of product. This limiting reagent determines the theoretical yield of the reaction. The other reactants are said to be non-limiting or in excess. This distinction makes sense only when the chemical equilibrium so favors the products to cause the complete consumption of one of the reactants.