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Limestone outcrops are recognized in the field by their softness (calcite and aragonite both have a Mohs hardness of less than 4, well below common silicate minerals) and because limestone bubbles vigorously when a drop of dilute hydrochloric acid is dropped on it. Dolomite is also soft but reacts only feebly with dilute hydrochloric acid, and ...
Limestone is a substitute for lime in many applications, which include agriculture, fluxing, and sulfur removal. Limestone, which contains less reactive material, is slower to react and may have other disadvantages compared with lime, depending on the application; however, limestone is considerably less expensive than lime.
Agricultural lime, also called aglime, agricultural limestone, garden lime or liming, is a soil additive made from pulverized limestone or chalk. The primary active component is calcium carbonate . Additional chemicals vary depending on the mineral source and may include calcium oxide .
In the lime industry, limestone is a general term for rocks that contain 80% or more of calcium or magnesium carbonate, including marble, chalk, oolite, and marl.Further classification is done by composition as high calcium, argillaceous (clayey), silicious, conglomerate, magnesian, dolomite, and other limestones. [5]
In the laboratory, a common example of effervescence is seen if hydrochloric acid is added to a block of limestone. If a few pieces of marble or an antacid tablet are put in hydrochloric acid in a test tube fitted with a bung, effervescence of carbon dioxide can be witnessed. CaCO 3 + 2 HCl → CaCl 2 + H 2 O + CO 2 ↑
Calcium hydroxide reacts with aluminium. This reaction is the basis of aerated concrete. [8] It does not corrode iron and steel, owing to passivation of their surface. Calcium hydroxide reacts with hydrochloric acid to give calcium hydroxychloride and then calcium chloride. In a process called sulfation, sulphur dioxide reacts with limewater:
It involves polishing the surface with an acidic solution and a steel wool pad on a flooring machine. The chemical reaction below shows a typical process using magnesium fluorosilicate (MgSiF 6) and hydrochloric acid (HCl) taking place. CaCO 3 (s) + MgSiF 6 (l) + 2HCl (l) → MgCl 2 (s) + CaSiF 6 (s) + CO 2 (g) + H 2 O(l)
This last reaction is consistent with the global lime sulfur reaction mentioned in the USDA document. [2] However, it does not account of all the details, a.o., the production of thiosulfate and sulfate amongst the end-products of the reaction. Meanwhile, it is a good first order approximation and it usefully highlights the overall lime sulfur ...