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The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships ...
Thermodynamics deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation.The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.
v. t. e. The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter. The law also defines the internal energy ...
The law was actually the last of the laws to be formulated. First law of thermodynamics. d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where. d U {\displaystyle dU} is the infinitesimal increase in internal energy of the system, δ Q {\displaystyle \delta Q} is the infinitesimal heat flow into the system, and.
The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system. However, the second law of thermodynamics is not a defining relation for the entropy.
t. e. The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
m = mass of each molecule (all molecules are identical in kinetic theory), γ (p) = Lorentz factor as function of momentum (see below) Ratio of thermal to rest mass-energy of each molecule: θ = k B T / m c 2 {\displaystyle \theta =k_ {\text {B}}T/mc^ {2}} K2 is the modified Bessel function of the second kind.
Chemical thermodynamics. Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of ...