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A chlorate candle, or an oxygen candle, is a cylindrical chemical oxygen generator that contains a mix of sodium chlorate and iron powder, which when ignited smolders at about 600 °C (1,100 °F), producing sodium chloride, iron oxide, and oxygen at a fixed rate of about 6.5 man-hours per kilogram of the mixture. The mixture has an indefinite ...
A perchlorate is a chemical compound containing the perchlorate ion, ClO − 4, the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary ammonium cations or other ions, for example, nitronium cation (NO + 2). The term perchlorate can also describe perchlorate esters or covalent ...
Of all the perchlorates, lithium perchlorate has both the highest oxygen to weight and oxygen to volume ratio, except beryllium diperchlorate which is expensive and toxic. The Vika system uses a canister containing about 1 liter (2.4 kg) of perchlorate to generate 600 liters (0.86 kg) of oxygen, enough for one person for one day.
Rubidium perchlorate can be obtained through the careful heating of a rubidium chlorate solution, leading to a disproportionation reaction with the release of oxygen gas: [3] 2 RbClO 3 → RbClO 4 + RbCl + O 2. When heated, it decomposes into the chloride and oxygen: [4] RbClO 4 → RbCl + 2 O 2. It has two polymorphs.
The chlorate was also measured in rainfall samples with the amount of chlorate similar to perchlorate. It is suspected that chlorate and perchlorate may share a common natural formation mechanism and could be a part of the chlorine biogeochemistry cycle. From a microbial standpoint, the presence of natural chlorate could also explain why there ...
Sodium perchlorate is the precursor to ammonium, potassium and lithium perchlorate salts, often taking advantage of their low solubility in water relative to NaClO 4 (209 g/(100 mL) at 25 °C). [6] It is used for denaturating proteins in biochemistry and in standard DNA extraction and hybridization reactions in molecular biology.
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