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In 2009, Zurek et al. predicted that the alloy LiH 6 would be a stable metal at only one quarter of the pressure required to metallize hydrogen, and that similar effects should hold for alloys of type LiH n and possibly "other alkali high-hydride systems", i.e. alloys of type XH n, where X is an alkali metal. [20]
The alkali metals also react similarly with hydrogen to form ionic alkali metal hydrides, where the hydride anion acts as a pseudohalide: these are often used as reducing agents, producing hydrides, complex metal hydrides, or hydrogen gas. [10]: 83 [65] Other pseudohalides are also known, notably the cyanides.
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a Group 1 is composed of hydrogen (H) and the alkali metals. Elements of the group have one s-electron in the outer electron shell. Hydrogen is not considered to be an alkali metal as it is not a metal, though it is more analogous to them than any other group. This makes the group somewhat exceptional.
The alkali metals (Li, Na, K, Rb, Cs, and Fr) are the most reactive metals in the periodic table - they all react vigorously or even explosively with cold water, resulting in the displacement of hydrogen. The Group 1 metal (M) is oxidised to its metal ions, and water is reduced to hydrogen gas (H 2) and hydroxide ion (OH −), giving a general ...
Many metals react with water to produce H 2, but the rate of hydrogen evolution depends on the metal, the pH, and the presence of alloying agents. Most often, hydrogen evolution is induced by acids. The alkali and alkaline earth metals, aluminium, zinc, manganese, and iron react readily with aqueous acids.
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
Hydrogen's ionization energy is very high (at 13.59844 eV), compared to the alkali metals. This is due to its single electron (and hence, very small electron cloud), which is close to the nucleus. Likewise, since there are not any other electrons that may cause shielding, that single electron experiences the full net positive charge of the nucleus.