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Enantioselective synthesis, also called asymmetric synthesis, [1] is a form of chemical synthesis.It is defined by IUPAC as "a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric (enantiomeric or diastereomeric) products in unequal amounts."
An autocatalytic reaction, a reaction in which the product acts as a catalyst for itself, serves as a model for homochirality. The asymmetric Soai reaction is commonly referred to as chemical plausibility for this pre-biotic hypothesis. In this system, an asymmetric amplification is observed during the process of autocatalytic catalysis.
This is a list of abbreviations used in law and legal documents. It is common practice in legal documents to cite other publications by using standard abbreviations for the title of each source. Abbreviations may also be found for common words or legal phrases.
Enantioselective ketone reductions convert prochiral ketones into chiral, non-racemic alcohols and are used heavily for the synthesis of stereodefined alcohols. [1]Carbonyl reduction, the net addition of H 2 across a carbon-oxygen double bond, is an important way to prepare alcohols.
In organic chemistry, regioselectivity is the preference of chemical bonding or breaking in one direction over all other possible directions. [1] [2] It can often apply to which of many possible positions a reagent will affect, such as which proton a strong base will abstract from an organic molecule, or where on a substituted benzene ring a further substituent will be added.
One of the most frequently employed methods for inducing enantio- or diastereoselectivity in the Henry reaction is the use of chiral metal catalysts, in which the nitro group and carbonyl oxygen coordinate to a metal that is bound to a chiral organic molecule. Some metals that have been used include zinc, cobalt, copper, magnesium, and chromium ...
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The term stereospecific reaction is ambiguous, since the term reaction itself can mean a single-mechanism transformation (such as the Diels–Alder reaction), which could be stereospecific, or the outcome of a reactant mixture that may proceed through multiple competing mechanisms, specific and non-specific.