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Iron sulfates occur as a variety of rare (commercially unimportant) minerals. Mikasaite, a mixed iron-aluminium sulfate of chemical formula (Fe 3+, Al 3+) 2 (SO 4) 3 [6] is the name of mineralogical form of iron(III) sulfate. This anhydrous form occurs very rarely and is connected with coal fires.
The sum of oxidation states in the ion equals its charge (as it equals zero for a neutral molecule). Also in anions, the formal (ionic) charges have to be considered when nonzero. For sulfate this is exemplified with the skeletal or Lewis structures (top), compared with the bond-order formula of all oxygens equivalent and fulfilling the octet ...
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ((NH 4) 2 Fe(SO 4) 2 ·6H 2 O). Iron(II) compounds tend to be oxidized to iron(III ...
Thus, the aquo ion is a weak acid, of comparable strength to acetic acid (pK a of about 4.8). This pK a is typical of the trivalent ions. The influence of the electronic configuration on acidity is shown by the fact that [Ru(H 2 O) 6] 3+ (pK a = 2.7) is more acidic than [Rh(H 2 O) 6] 3+ (pK a = 4), despite the fact that Rh(III) is expected to ...
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
Polyatomic ions containing oxygen, such as carbonate and sulfate, are called oxyanions. Molecular ions that contain at least one carbon to hydrogen bond are called organic ions. If the charge in an organic ion is formally centred on a carbon, it is termed a carbocation (if positively charged) or carbanion (if negatively charged).
For example, comparing the potentials for zinc (-0.75 V) with those of iron (Fe(II) -0.47 V, Fe(III) -0.06 V) it is seen that iron ions are more easily reduced than zinc ions. This is the basis for using zinc to provide anodic protection for large structures made of iron or to protect small structures by galvanization.
In the absence of EDTA or similar chelating agents, ferric ions form insoluble solids and are thus not bioavailable. [1] Together with pentetic acid (DTPA), EDTA is widely used for sequestering metal ions. Otherwise these metal ions catalyze the decomposition of hydrogen peroxide, which is used to bleach pulp in papermaking. Several million ...