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The dependence of work on the path of the thermodynamic process is also unrelated to reversibility, since expansion work, which can be visualized on a pressure–volume diagram as the area beneath the equilibrium curve, is different for different reversible expansion processes (e.g. adiabatic, then isothermal; vs. isothermal, then adiabatic ...
Equations of mechanics are reversible in time, hence, the reverse collisions obey the same laws. This reversibility of collisions is the first example of microreversibility. According to Boltzmann, this microreversibility implies the principle of detailed balance for collisions: at the equilibrium ensemble each collision is equilibrated by its ...
In physics, Loschmidt's paradox (named for J.J. Loschmidt), also known as the reversibility paradox, irreversibility paradox, or Umkehreinwand (from German 'reversal objection'), [1] is the objection that it should not be possible to deduce an irreversible process from time-symmetric dynamics.
The laws of thermodynamics are a set of scientific laws ... These relations are derived from statistical mechanics under the principle of microscopic reversibility ...
A Markov process is called a reversible Markov process or reversible Markov chain if there exists a positive stationary distribution π that satisfies the detailed balance equations [13] =, where P ij is the Markov transition probability from state i to state j, i.e. P ij = P(X t = j | X t − 1 = i), and π i and π j are the equilibrium probabilities of being in states i and j, respectively ...
In 1864, Peter Waage and Cato Maximilian Guldberg formulated their law of mass action which quantified Berthollet's observation. Between 1884 and 1888, Le Chatelier and Braun formulated Le Chatelier's principle , which extended the same idea to a more general statement on the effects of factors other than concentration on the position of the ...
Landauer's principle (and indeed, the second law of thermodynamics) can also be understood to be a direct logical consequence of the underlying reversibility of physics, as is reflected in the general Hamiltonian formulation of mechanics, and in the unitary time-evolution operator of quantum mechanics more specifically. [8]
T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, :. Since the second law of thermodynamics states that entropy increases as time flows toward the future, in general, the macroscopic universe does not show symmetry under time reversal. In other words, time is said to be ...