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Another macroscopic consequence of microscopic reversibility is the symmetry of kinetic coefficients, the so-called reciprocal relations. The reciprocal relations were discovered in the 19th century by Thomson and Helmholtz for some phenomena but the general theory was proposed by Lars Onsager in 1931. [ 6 ]
A Markov process is called a reversible Markov process or reversible Markov chain if there exists a positive stationary distribution π that satisfies the detailed balance equations [13] =, where P ij is the Markov transition probability from state i to state j, i.e. P ij = P(X t = j | X t − 1 = i), and π i and π j are the equilibrium probabilities of being in states i and j, respectively ...
Based on the principle of microscopic reversibility, the inert nature of the neopentyl halides towards the S N 2 reaction indicates that an S N 2 reaction is unlikely to be the mechanism for the synthesis of the neopentyl halides in this reaction.
In physics, the cross section is a measure of the probability that a specific process will take place in a collision of two particles. For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during an interaction with an atomic nucleus.
The theory developed by Onsager is much more general than this example and capable of treating more than two thermodynamic forces at once, with the limitation that "the principle of dynamical reversibility does not apply when (external) magnetic fields or Coriolis forces are present", in which case "the reciprocal relations break down". [1]
T-symmetry or time reversal symmetry is the theoretical symmetry of physical laws under the transformation of time reversal, :. Since the second law of thermodynamics states that entropy increases as time flows toward the future, in general, the macroscopic universe does not show symmetry under time reversal.
Nuclear cross sections are used in determining the nuclear reaction rate, and are governed by the reaction rate equation for a particular set of particles (usually viewed as a "beam and target" thought experiment where one particle or nucleus is the "target", which is typically at rest, and the other is treated as a "beam", which is a projectile with a given energy).
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