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  2. Cannizzaro reaction - Wikipedia

    en.wikipedia.org/wiki/Cannizzaro_reaction

    2 C 6 H 5 CHO + KOH → C 6 H 5 CH 2 OH + C 6 H 5 COOK. The process is a redox reaction involving transfer of a hydride from one substrate molecule to the other: one aldehyde is oxidized to form the acid, the other is reduced to form the alcohol. [3]

  3. Potassium hydroxide - Wikipedia

    en.wikipedia.org/wiki/Potassium_hydroxide

    Entomologists wishing to study the fine structure of insect anatomy may use a 10% aqueous solution of KOH to apply this process. [24] In chemical synthesis, the choice between the use of KOH and the use of NaOH is guided by the solubility or keeping quality of the resulting salt.

  4. Lye - Wikipedia

    en.wikipedia.org/wiki/Lye

    Pellets of soda lye (sodium hydroxide) Pellets of potash lye (potassium hydroxide)Lye is a hydroxide, either sodium hydroxide or potassium hydroxide.The word lye most accurately refers to sodium hydroxide (NaOH), [citation needed] but historically has been conflated to include other alkali materials, most notably potassium hydroxide (KOH).

  5. Alcohol oxidation - Wikipedia

    en.wikipedia.org/wiki/Alcohol_oxidation

    Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters. The reaction mainly applies to primary and secondary alcohols. Secondary alcohols form ketones, while primary alcohols form aldehydes or carboxylic acids. [1] A variety of oxidants can be used.

  6. Williamson ether synthesis - Wikipedia

    en.wikipedia.org/wiki/Williamson_ether_synthesis

    This reaction is important in the history of organic chemistry because it helped prove the structure of ethers. The general reaction mechanism is as follows: [3] An example is the reaction of sodium ethoxide with chloroethane to form diethyl ether and sodium chloride: C 2 H 5 Cl + C 2 H 5 ONa → C 2 H 5 OC 2 H 5 + NaCl

  7. Hydroxyl value - Wikipedia

    en.wikipedia.org/wiki/Hydroxyl_value

    The hydroxyl value can be calculated using the following equation. Note that a chemical substance may also have a measurable acid value affecting the measured endpoint of the titration. The acid value ( AV ) of the substance, determined in a separate experiment, enters into this equation as a correction factor in the calculation of the hydroxyl ...

  8. Koch reaction - Wikipedia

    en.wikipedia.org/wiki/Koch_reaction

    The Koch reaction is an organic reaction for the synthesis of tertiary carboxylic acids from alcohols or alkenes and carbon monoxide. Some commonly industrially produced Koch acids include pivalic acid , 2,2-dimethylbutyric acid and 2,2-dimethylpentanoic acid. [ 1 ]

  9. Equivalent concentration - Wikipedia

    en.wikipedia.org/wiki/Equivalent_concentration

    There are three common types of chemical reaction where normality is used as a measure of reactive species in solution: In acid-base chemistry, normality is used to express the concentration of hydronium ions (H 3 O +) or hydroxide ions (OH −) in a solution. Here, ⁠ 1 / f eq ⁠ is an integer value. Each solute can produce one or more ...