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Within chemistry, a Job plot, otherwise known as the method of continuous variation or Job's method, is a method used in analytical chemistry to determine the stoichiometry of a binding event. The method is named after Paul Job and is also used in instrumental analysis and advanced chemical equilibrium texts and research articles.
The continuous stirred-tank reactor (CSTR), also known as vat-or backmix reactor, mixed flow reactor (MFR), or a continuous-flow stirred-tank reactor (CFSTR), is a common model for a chemical reactor in chemical engineering and environmental engineering. A CSTR often refers to a model used to estimate the key unit operation variables when using ...
A disorder-broadened first-order transition occurs over a finite range of temperatures where the fraction of the low-temperature equilibrium phase grows from zero to one (100%) as the temperature is lowered. This continuous variation of the coexisting fractions with temperature raised interesting possibilities.
For temperature variation the thermal mass of the reactor as well as peripherals such as fluid baths needs to be considered. More often than not, the analysis time needs to be considered. Segmented flow is an approach that improves upon the speed in which screening, optimization, and libraries can be conducted in flow chemistry.
Suppose we are given a Hilbert space and a Hermitian operator over it called the Hamiltonian.Ignoring complications about continuous spectra, we consider the discrete spectrum of and a basis of eigenvectors {| } (see spectral theorem for Hermitian operators for the mathematical background): | =, where is the Kronecker delta = {, =, and the {| } satisfy the eigenvalue equation | = | .
S T Epstein 1974 "The Variation Method in Quantum Chemistry". (New York: Academic) C Lanczos, The Variational Principles of Mechanics (Dover Publications) R K Nesbet 2003 "Variational Principles and Methods In Theoretical Physics and Chemistry". (New York: Cambridge U.P.)
In mathematics, the direct method in the calculus of variations is a general method for constructing a proof of the existence of a minimizer for a given functional, [1] introduced by Stanisław Zaremba and David Hilbert around 1900. The method relies on methods of functional analysis and topology. As well as being used to prove the existence of ...
Calculus of variations is concerned with variations of functionals, which are small changes in the functional's value due to small changes in the function that is its argument. The first variation [l] is defined as the linear part of the change in the functional, and the second variation [m] is defined as the quadratic part. [22]