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The same catalytic effect of the alkali hydroxides (function of the Na 2 O eq content of cement) also contributes to the carbonatation of portlandite by atmospheric CO 2 in concrete although the rate of propagation of the reaction front is there essentially limited by the CO 2 diffusion within the concrete matrix less porous. [16]
The speed of carbonation depends primarily on the porosity of the concrete and its moisture content. Carbonation in concrete pores happens only at a relative humidity (RH) of 40-90%—when RH is higher than 90%, carbon dioxide cannot enter the concrete pores, and when RH is lower than 40%, CO 2 cannot be dissolved in water. [28]
Bacterial activity in sewers – anaerobic sulfate reduction at work in the organic-rich sludges accumulated under water in the conduits produces hydrogen sulfide gas (H 2 S). After its released in the air of the galleries, H 2 S is further oxidized into sulfuric acid by atmospheric oxygen.
A reducing atmosphere is also used to produce specific effects on ceramic wares being fired. A reduction atmosphere is produced in a fuel fired kiln by reducing the draft and depriving the kiln of oxygen. This diminished level of oxygen causes incomplete combustion of the fuel and raises the level of carbon inside the kiln.
Corrosion may occur where stale sewage generates hydrogen sulfide gas into an atmosphere containing oxygen gas and high relative humidity. There must be an underlying anaerobic aquatic habitat containing sulfates and an overlying aerobic aquatic habitat separated by a gas phase containing both oxygen and hydrogen sulfide at concentrations in excess of 2 ppm.
When atmospheric carbon dioxide (CO 2), or carbonate ions (HCO − 3, CO 2− 3 dissolved in water) diffuse into concrete from its external surface, they react with calcium hydroxide (portlandite, Ca(OH) 2) and the pH of the concrete pore water progressively decreases from 13.5 – 12.5 to 8.5 (pH of water in equilibrium with calcite).
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
The reaction using titanium dioxide shows a greater oxidizing power than most other metal-based catalysts. Photo-catalytic blocks have replaced ordinary paving in around 30 towns in Japan , originally having been tested in Osaka in 1997 and have been used in the City of Westminster (London) [ citation needed ] .