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Formate is a common C-1 source in living systems. It is formed from many precursors including choline, serine, and sarcosine. It provides a C-1 source in the biosynthesis of some nucleic acids. Formate (or formic acid) is invoked as a leaving group in the demethylation of some sterols. [2]
Rhodium(II) acetate is the coordination compound with the formula Rh 2 (AcO) 4, where AcO − is the acetate ion (CH 3 CO − 2). This dark green powder is slightly soluble in polar solvents, including water. It is used as a catalyst for cyclopropanation of alkenes. It is a widely studied example of a transition metal carboxylate complex. [2]
An example total ion current chromatogram from an LC-MS analysis. The total ion current chromatogram (TICC) represents the summed intensity across the entire range of masses being detected at every point in the analysis. [2] [3] The range is typically several hundred mass-to-charge units or more. In complex samples, the TICC often provides ...
MS is an experiment that must take place in gas phase and under vacuum (1.33 * 10 −2 to 1.33 * 10 −6 pascal). Therefore, the development of devices facilitating the transition from samples at higher pressure and in condensed phase (solid or liquid) into a vacuum system has been essential to develop MS as a potent tool for identification and ...
Dppf readily forms metal complexes. [2] The palladium derivative, (dppf)PdCl 2, which is popular for palladium-catalyzed coupling reactions, is prepared by treating dppf with the acetonitrile or benzonitrile adducts of palladium dichloride: [2] Substitution of the phenyl substituents in dppf leads to derivatives with modified donor-acceptor properties at the phosphorus atoms.
A good example is the formation of adducts between the Lewis acid borane and the oxygen atom in the Lewis bases, tetrahydrofuran (THF): BH 3 ·O(CH 2) 4 or diethyl ether: BH 3 ·O(CH 3 CH 2) 2. Many Lewis acids and Lewis bases reacting in the gas phase or in non-aqueous solvents to form adducts have been examined in the ECW model. [3]
Ion suppression in LC-MS and LC-MS/MS refers to reduced detector response, or signal:noise as a manifested effect of competition for ionisation efficiency in the ionisation source, between the analyte(s) of interest and other endogenous or exogenous (e.g. plasticisers extracted from plastic tubes, [1] mobile phase additives) species which have not been removed from the sample matrix during ...
This format was one of the earliest attempts to supply a standardized file format for data exchange in mass spectrometry. JCAMP-DX was initially developed for infrared spectrometry. JCAMP-DX is an ASCII based format and therefore not very compact even though it includes standards for file compression. JCAMP was officially released in 1988. [2]