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One reactant (A) is chosen, and the balanced chemical equation is used to determine the amount of the other reactant (B) necessary to react with A. If the amount of B actually present exceeds the amount required, then B is in excess and A is the limiting reagent. If the amount of B present is less than required, then B is the limiting reagent.
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
The limiting reagent is the reagent that limits the amount of product that can be formed and is completely consumed when the reaction is complete. An excess reactant is a reactant that is left over once the reaction has stopped due to the limiting reactant being exhausted.
Stoichiometric equations are used to determine the limiting reagent or reactant—the reactant that is completely consumed in a reaction. The limiting reagent determines the theoretical yield—the relative quantity of moles of reactants and the product formed in a chemical reaction. Other reactants are said to be present in excess.
From the general mole balance on some species , where for a CSTR steady state and perfect mixing are assumed, + = + = = Assuming a constant volumetric flow rate , which is the case for a liquid reactor or a gas phase reaction with no net generation of moles,
Another example is the unimolecular nucleophilic substitution (S N 1) reaction in organic chemistry, where it is the first, rate-determining step that is unimolecular. A specific case is the basic hydrolysis of tert-butyl bromide (t-C 4 H 9 Br) by aqueous sodium hydroxide. The mechanism has two steps (where R denotes the tert-butyl radical t-C ...
The color-change that occurs in the blue bottle experiment has features of a clock reaction, in which a visible change in the concentration of one or more reagents suddenly occurs upon the exhaustion of a limiting reagent. For example, the limiting reactant, oxygen, is consumed by another reactant, benzoin, with the help of safranin as a ...
Examples are those involving catalysis and enzymatic reactions. Heterogeneous reactions where reactants are in different phases are also candidates for diffusion control. One classical test for diffusion control of a heterogeneous reaction is to observe whether the rate of reaction is affected by stirring or agitation; if so then the reaction ...