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By the principle of minimum energy, there are a number of other state functions which may be defined which have the dimensions of energy and which are minimized according to the second law under certain conditions other than constant entropy. These are called thermodynamic potentials. For each such potential, the relevant fundamental equation ...
Mass–energy equivalence states that all objects having mass, or massive objects, have a corresponding intrinsic energy, even when they are stationary.In the rest frame of an object, where by definition it is motionless and so has no momentum, the mass and energy are equal or they differ only by a constant factor, the speed of light squared (c 2).
The energy efficiency of a process involving chemical change may be expressed relative to these theoretical minima or maxima.The difference between the change of enthalpy and the change of Gibbs energy of a chemical transformation at a particular temperature indicates the heat input required or the heat removal (cooling) required to maintain ...
There are some notable similarities in equations for momentum, energy, and mass transfer [7] which can all be transported by diffusion, as illustrated by the following examples: Mass: the spreading and dissipation of odors in air is an example of mass diffusion. Energy: the conduction of heat in a solid material is an example of heat diffusion.
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Transfers of energy as work, or as heat, or of matter, between the system and the surroundings, take place through the walls, according to their respective permeabilities. Matter or energy that pass across the boundary so as to effect a change in the internal energy of the system need to be accounted for in the energy balance equation.
Mathematical notation is widely used in mathematics, science, and engineering for representing complex concepts and properties in a concise, unambiguous, and accurate way. For example, the physicist Albert Einstein's formula = is the quantitative representation in mathematical notation of mass–energy equivalence. [1]
The internal energy of a thermodynamic system is the energy of the system as a state function, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization.