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Refining is achieved by electrolysis, which exploits the easy (low potential) and selective conversion of copper(II) solutions to the metal. The anodes cast from processed blister copper are placed into an aqueous solution of 3–4% copper sulfate and 10–16% sulfuric acid .
A modern copper refinery tankhouse using IsaKidd technology. The IsaKidd Technology is a copper electrorefining and electrowinning technology that was developed independently by Copper Refineries Proprietary Limited (“CRL”), a Townsville, Queensland, subsidiary of MIM Holdings Limited (which is now part of the Glencore group of companies), and at the Falconbridge Limited (“Falconbridge ...
Electrorefining copper. Electrowinning is the oldest industrial electrolytic process. The English chemist Humphry Davy obtained sodium metal in elemental form for the first time in 1807 by the electrolysis of molten sodium hydroxide. Electrorefining of copper was first demonstrated experimentally by Maximilian, Duke of Leuchtenberg in 1847. [2]
Electrolysis is usually done in bulk using hundreds of sheets of metal connected to an electric power source. In the production of copper, these pure sheets of copper are used as starter material for the cathodes, and are then lowered into a solution such as copper sulfate with the large anodes that are cast from impure (97% pure) copper.
The copper is extracted from the solvent with strong aqueous acid which then deposits pure copper onto cathodes using an electrolytic procedure (electrowinning). SX/EW processing is best known for its use by the copper industry, where it accounts for 20% of worldwide production, but the technology is also successfully applied to a wide range of ...
The purest copper is obtained by an electrolytic process, undertaken using a slab of impure copper as the anode and a thin sheet of pure copper as the cathode. The electrolyte is an acidic solution of copper (II) sulfate. By passing electricity through the cell, copper is dissolved from the anode and deposited on the cathode. However ...
Sometimes, however, further refining is needed to produce ultra-high purity metals. The main types of metal recovery processes are electrolysis, gaseous reduction, and precipitation. For example, a major target of hydrometallurgy is copper, which is conveniently obtained by electrolysis.
The electrolysis can be done on a molten metal oxide (smelt electrolysis) which is used for example to produce aluminium from aluminium oxide via the Hall-Hérault process. Electrolysis can be used as a final refining stage in pyrometallurgical metal production (electrorefining) and it is also used for reduction of a metal from an aqueous metal ...