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Organoselenium chemistry is the science exploring the properties and reactivity of organoselenium compounds, chemical compounds containing carbon-to-selenium chemical bonds. [1] [2] [3] Selenium belongs with oxygen and sulfur to the group 16 elements or chalcogens, and similarities in chemistry are to be expected. Organoselenium compounds are ...
Selenium forms two oxides: selenium dioxide (SeO 2) and selenium trioxide (SeO 3). Selenium dioxide is formed by the reaction of elemental selenium with oxygen: [5] + It is a polymeric solid that forms monomeric SeO 2 molecules in the gas phase. It dissolves in water to form selenous acid, H 2 SeO 3.
Selenium dioxide is the chemical compound with the formula SeO 2. This colorless solid is one of the most frequently encountered compounds of selenium . It is used in making specialized glasses as well as a reagent in organic chemistry.
This process leaches natural soluble selenium compounds (such as selenates) into the water, which may then be concentrated in wetlands as the water evaporates. Selenium pollution of waterways also occurs when selenium is leached from coal flue ash, mining and metal smelting , crude oil processing, and landfill. [ 103 ]
Following rearrangement and loss of water, a second equivalent of water attacks the alpha position. Red amorphous selenium is liberated in the final step to give the 1,2-dicarbonyl product. [8] [9]: 4331 Allylic oxidation using selenium-dioxide proceeds via an ene reaction at the electrophilic selenium center.
Carbon dioxide – CO 2; Carbon disulfide – CS 2; Carbon monoxide – CO; Carbon tetrabromide – CBr 4; Carbon tetrachloride – CCl 4; Carbon tetrafluoride – CF 4; Carbon tetraiodide – CI 4; Carbonic acid – H 2 CO 3; Carbonyl chloride – COCl 2; Carbonyl fluoride – COF 2; Carbonyl sulfide – COS; Carboplatin – C 6 H 12 N 2 O 4 Pt
It is a white solid. This compound features a rare example of a stable, unhindered carbon-selenium double bond. The compound is used in the synthesis of selenium heterocycles. Selenourea is a selenium analog of urea O=C(NH 2) 2. Few studies have been done on the compound due to the instability and toxicity of selenium compounds. [1]
For example, in phosphorus pentafluoride (PF 5), 5 resonance structures can be generated each with four covalent bonds and one ionic bond with greater weight in the structures placing ionic character in the axial bonds, thus satisfying the octet rule and explaining both the observed trigonal bipyramidal molecular geometry and the fact that the ...