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Boyle's law demonstrations. The law itself can be stated as follows: For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa ...
A modern body plethysmograph using ultrasound. A plethysmograph is an instrument for measuring changes in volume within an organ or whole body (usually resulting from fluctuations in the amount of blood or air it contains). The word is derived from the Greek "plethysmos" (increasing, enlarging, becoming full), and "graphein" (to write).
Charles's law (also known as the law of volumes) is an experimental gas law that describes how gases tend to expand when heated. A modern statement of Charles's law is: When the pressure on a sample of a dry gas is held constant, the Kelvin temperature and the volume will be in direct proportion. [1] This relationship of direct proportion can ...
Boyle's law was one of the earliest formulation of an equation of state. In 1662, the Irish physicist and chemist Robert Boyle performed a series of experiments employing a J-shaped glass tube, which was sealed on one end. Mercury was added to the tube, trapping a fixed quantity of air in the short, sealed end of the tube. Then the volume of ...
e. Gay-Lussac's law usually refers to Joseph-Louis Gay-Lussac 's law of combining volumes of gases, discovered in 1808 and published in 1809. [1] However, it sometimes refers to the proportionality of the volume of a gas to its absolute temperature at constant pressure. The latter law was published by Gay-Lussac in 1802, [2] but in the article ...
Thermodynamics. In thermodynamics, the compressibility factor (Z), also known as the compression factor or the gas deviation factor, describes the deviation of a real gas from ideal gas behaviour. It is simply defined as the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and pressure.
This form of the ideal gas law is very useful because it links pressure, density, and temperature in a unique formula independent of the quantity of the considered gas. Alternatively, the law may be written in terms of the specific volume v, the reciprocal of density, as. It is common, especially in engineering and meteorological applications ...
The Boyle temperature is formally defined as the temperature for which the second virial coefficient, , becomes zero. It is at this temperature that the attractive forces and the repulsive forces acting on the gas particles balance out. This is the virial equation of state and describes a real gas. Since higher order virial coefficients are ...